Nanomaterials free fulltext cellulose nanofibrilcarbon. In this study, aminofunctionalized multiwalled carbon nanotubes mwcntsnh 2 were successfully synthesized via an improved method and used for removal of organic dyes in aqueous solution. Adsorption of tannery anionic dyes by modified kaolin from aqueous solution article pdf available in desalination and water treatment 57. Adsorption of an anionic dye from aqueous medium by organoclays. Fixedbed system for adsorption of anionic acid dyes from. Adsorption of cationic and anionic surfactants on natural and. Until now, in order to increase the adsorption capacity of anionic dyes from wastewater using zeolite, its surface has been modified with various agents, such as ctab. Functionalized mesoporous silica material and anionic dye. Given that the issues and essential requirements for dye adsorbents, in this study, hierarchical porous chitosan sponges as adsorbents for adsorption of rose bengal rb, a. The synthesized mwcntsnh 2 were characterized by fourier transform infrared ftir spectroscopy, thermogravimetric analysis tga, scanning electron microscope sem, etc. Ying sun, feng ying bai, xue min wang, yu wang, li xian sun, yong heng xing. Jul 07, 2011 the present study aims to investigate the adsorption of anionic dye, alizarin red s ars, on activated clay modified by iron oxide feclay in a batch reactor. Adsorption of four anionic dyes on the fly ash was found to be dependent on the initial ph of solution.
The present model study deals with the adsorption of a model anionic dye, eosin y, from wastewater using conditioned chitosan hydrobeads. Electrocoagulationadsorption to remove anionic and cationic. Papaya seed ps was modified using chemically esterification of carboxyl group to improve performance in adsorption capacity for removal cationic and anionic dye from aquoues solution. Jamil, c maytham kadhim obaid, a,b and thomas shean yaw choong a water pollution due to the effluents from textile industries causes serious concern around the world. An attempt was made to chemically quaternized kcf qkcf as an adsorbent to increase adsorption affinity towards anionic reactive redrb dye rr. Layered anionic clay mgal was synthesized from anhydrous alcl. Department of chemical and biomolecular engineering, rice university, houston, tx, usa. Response surface methodology optimization akash deb department of civil engineering, national institute of technology agartala, jirania, west tripura, 799046 india. Effective adsorption of anionic dye, alizarin red s, from. Pdf cationic and anionic dye adsorption by agricultural. Adsorption of an anionic azo dye using moringa oleifera seed. Adsorption of anionic azo dyes from aqueous solutions onto. Adsorption and desorption kinetics of anionic dyes on doped.
Being a biopolymer, sodium alginate is expected to offer biocompatibility to the synthesized clayalginate composite adsorbents. In this study, the commercial mmt was modified with mosp to create a new selective organmontmorillonite for anionic dye adsorption. Adsorption of an anionic dye congo red from aqueous. Pdf adsorption of an anionic dye from aqueous medium by. Two classes of carbon nanomaterials, carbon nanotubes. Coadsorption of an anionic dye in the presence of a cationic dye and a heavy metal ion by graphene oxide and photoreduced graphene oxide xiaorong zhang,ab chengbing qin, ab yani gong,ab yunrui song,ab guofeng zhang,ab ruiyun chen,ab yan gao,ab liantuan xiaoab and suotang jiaab. This may be associated with increased mobility of dye moieties with a rise in temperature, due to which the probability of anionic and cationic dyes interaction increases with each. Hierarchical porous chitosan sponges as robust and.
Nov 11, 2019 batch adsorption experiments were conducted in a thermostatic orbital water bath shaker unitronicor selecta, spain at a shaking rate of 100 rpm. Concurrent adsorption of cationic and anionic dyes from. Themanufactureof azo dyes can impacttheenvironment. The langmuir, freundlich, and the equilibrium adsorption isotherms of rr dye adsorption onto qkcf are shown in figures 11 respectively. Dec 22, 2017 given that the issues and essential requirements for dye adsorbents, in this study, hierarchical porous chitosan sponges as adsorbents for adsorption of rose bengal rb, a toxic anionic dye, are. The maximum adsorption capacity of the composite was enhanced by 51% for acid green 25 and 160% for acid green 27, compared to the pristine layered clay sample. Adsorbent characterizations were investigated using infrared spectroscopy and xray diffraction. Adsorption of cationic and anionic dyes onto commercial kaolin. Layered clayalginate composites for the adsorption of. Adsorptive removal of anionic dye from aqueous solutions by. It was found that the doped pani selectively adsorbs anionic dyes and does not adsorb. Cationic and anionic dye adsorption by agricultural solid wastes. Continuous flow removal of anionic dyes in water by chitosan.
Xray diffraction studies of the pristine clays and dye loaded clays indicate both anion exchange and physical adsorption were involved in the orange ii uptake process however, uptake of acid blue 1 was solely due to physical adsorption. Coadsorption of an anionic dye in the presence of a. Experimental results revealed that optimal adsorption took place at basic ph. Request pdf adsorption of anionic and cationic dyes on activated carbons with different surface chemistries the influence of the surface chemical groups of an activated carbon on the removal. The adsorption of anionic dyes causes the variation in electrical conductivity of pani, indicating its potential as a conductometric sensor for these dyes at very low concentration. Nc was used as adsorbent for removal of methyl orange mo and eosin yellow ey dye from binary dye matrix under ultrasonic. The adsorption behavior of two reactive dyes reactive red 23 and reactive blue 171 and two acid dyes acid black 1 and acid blue193 from aqueous solution on fly ash was investigated in order to identify the ability of this wastematerial to remove. Coadsorption of an anionic dye in the presence of a cationic.
The effect of surfactant concentration, surfactant ionic headgroup, and surfactant hydrophobic tail were investigated in detail. The operation parameters investigated included initial concentrations, 50500 mgl and various adsorbent nps and eps. Talbi 1 1labo r a to i edch mana lyq up sic ch m ex,d p te nf cs ce b n msik casablanca, maroc. It is found that the cationic cpc exhibits negligible adsorption on synthetic cal. The maximum adsorption capacity of the composite was enhanced by 51% for acid green 25 and 160% for acid. Adsorption and desorption kinetics of anionic dyes on. Dependence of absorption performance on essential factors, such as initial dye concentration, temperature and initial ph, are experimentally.
Aminofunctionalized multiwalled carbon nanotubes as. Adsorption of the anionic dye eosin y by chitosan can be attributed to the interaction between the protonated amine group of chitosan r nh 2 and the anionic group of the dye d co 2 na molecule. The experimental data were analyzed by using langmuir and freundlich models of. Such a hydrophilic, anionic macroporous material exhibited excellent adsorption properties for cationic dyes. Fixedbed system for adsorption of anionic acid dyes from binary solution onto quaternized kenaf core fiber. Kinetic mechanism of competitive adsorption of disperse. Adsorption of anionic dye by anionic surfactant modified. In this chapter, we discuss our recent studies on synthesis of anionic clays with various compositions mgal, znal and nial and concentrations and their application for the removal of acid dyes from water.
Removal of reactive anionic dyes from binary solutions by. Moreover, the parameters affecting the adsorption including. Effect of cationic and anionic dye adsorption from aqueous ipcbee anionic dye cr and eps can be remarkable as excellent adsorbent modified of ps for cationic dye removal. Cationic and anionic dye adsorption by agricultural solid. Enhanced adsorption removal of anionic dyes via a facile. The equilibrium data matched well with the langmuir isotherm model, which indicated monolayer dye adsorption onto the adsorbent surface.
The process of sorption is being increasingly used for ecofriendly and economic remediation of textile dye effluents. Influence of solution ph on dye uptake by the clay adsorbents and on equilibrium ph of the solution after. Kenaf core fiber kcf is a natural cellulose fiber derived from the plant and it is an important raw material for a variety of products. Adsorption of anionic and cationic dyes on activated. Hence, the main objective of this paper is to test the anionic dye adsorption of the moringa oleifera seed proteinmontmorillonite mospmmt composite. Pdf adsorption of anionic dyes from aqueous solution on. This is also observed in alkaline ph since the amino groups of the polymer are deprotonated. The effect of chitosan concentration coated on luffa fiber and initial anionic dye concentrations had been investigated on adsorption equilibrium and adsorption kinetic. The organoattapulgite was prepared using hexadecyltrimethylammonium bromide htmab with equation equivalent ratio of htmab to cec of attapulgite added and then used as adsorbent for the removal of congo red cr anionic dye from aqueous solution. Adsorption of anionic dyes on the biopolymer chitin.
Here, hybrid aerogels are assembled from cellulose nanofibrils cnfs and carbon nanomaterials to remove cationic dye methylene blue mb and anionic dye congo red cr in single and binary systems. Intidhar jabir idan, a,b, luqman chuah abdullah, a siti nurul ain binti md. Cetylpyridinium chloride cpc and sodium dodecyl sulfate sds are chosen as typical cationic and anionic surfactants, respectively. Effect of cationic and anionic dye adsorption from aqueous. The present study aims to investigate the adsorption of anionic dye, alizarin red s ars, on activated clay modified by iron oxide feclay in a batch reactor.
Adsorption of two representative anionic dyes acid fuchsine af and acid orange ii ao using mcm41 functionalized with amine groups in a mesoporous silica framework nh2mcm41 as the adsorbent was investigated. Adsorption of anionic dye is favored at ph adsorption of anionic dyes from aqueous solution on fly. Adsorption of an anionic azo dye using moringa oleifera. Several several previous studies on cr dye adsorption o nto ground nut shell char coal 46 and. Mariam sumari, yamin yasin, zaini hamzah faculty of applied sciences, universiti teknologi mara, 40450, shah alam, selangor corresponding author. Adsorption behavior of the modified activated carbon from aqueous solution was investigated by varying the parameters such as ph, contact time and amaranth concentration, and the optimum adsorption ph was 1. Adsorption study for removal of congo red anionic dye using. Excellent mo and ey dye removal more than 98% was observed from binary matrix at a wide solution ph from 2. The maximum adsorption capacity of the monolith for methylene blue mb and malachite green mg reached 1,316 and 2,624 mgg, respectively, in 500800 mgl dye solution at 25c.
Anionic dye adsorption from aqueous solutions by chitosan. Removal of a cationic dye from wastewater by adsorption. Adsorption of anionicnonionic and cationicnonionic surfactant mixtures on kaolinite qun xu, t. Abstract magnesium hydroxidecoated pyrolytic biochar composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye directly frozen yellow onto magnesium hydroxidecoated pyrolytic biochar was investigated in the batch mode. Batch adsorption experiments were conducted in a thermostatic orbital water bath shaker unitronicor selecta, spain at a shaking rate of 100 rpm. Desorption of dyes suggested the predominant adsorption mechanisms, that is, chemisorption for anionic dyes. Adsorption of anionic dye using cationic surfactant.
Continuous flow removal of anionic dyes in water by. As the obtained isotherm parameters show, qkcf has a high adsorption capacity for anionic rr dye in the solution. Adsorption study for removal of congo red anionic dye. The kinetic experiments were carried out separately for four different initial dye. Decreasing the ph of the solution makes more protons available to protonate the. Adsorption of cationic and anionic surfactants on carbonate materials is investigated in this study. Competitive adsorption increased the time of attaining equilibrium of disperse dye. Jamil5 1department of chemical and environmental engineering, faculty of engineering, universiti putra malaysia, selangor, malaysia.
Adsorption of an anionic dye, remazole brilliant blue r rbbr from aqueous solution, on organically modified attapulgite atp and bentonite bnt clays was investigated. Adsorption of anionic and cationic dyes by activated carbons. Adsorptive removal of anionic dye from aqueous solutions. In this study, we report an approach for the adsorption and desorption of anionic sulfonated dyes from aqueous solution by doped polyaniline. However, the adsorption of anionic reactive dyes using natural zeolite is very limited due to the surface of the zeolite and the dye molecules having negative charges. The adsorption process reached equilibrium within 90 min, and the removal efficiency increased with the enhancement of initial dye concentration, adsorbent dosage, and contact time, but decreased with the enhancement of solution. The adsorption process reached equilibrium within 90 min, and the removal efficiency increased with the enhancement of initial dye concentration, adsorbent dosage, and contact time, but decreased with the enhancement of solution ph. To extend the application of the current method, we performed further adsorption experiments using other anionic dyes of different colors cy5. Removal of a cationic dye from wastewater by adsorption onto natural adsorbents h. Comparing the thermodynamic parameters of adsorption of a dye from a single dye solution to binary dye solution shows higher values of. Adsorption of acid dyes on hydrotalcitelike anionic clays. Pdf adsorption of tannery anionic dyes by modified. Kinetic mechanism of competitive adsorption of disperse dye.
The adsorbed dyes were desorbed from the polymer by using a basic aqueous solution. The fourier transform infrared spectroscopy, xray diffraction spec. Kenaf is a widely cultivated crop, particularly in the tropics. Advances in nanoscale science and engineering are providing new opportunities to develop promising adsorbents for environmental remediation. Adsorption of anionic amido black dye by layered double hydroxide, znalco3ldh s. The most challenging mission in wastewater treatment plants is the removal of anionic dyes, because they are watersoluble and produce very shining colours in the water. Adsorption of anionic dye using cationic surfactantmodified kenaf core fibers intidhar jabir idan1,2, luqman chuah abdullah1,3, dalia sadiq mahdi4, maytham kadhim obaid1,2, siti nurul ain binti md. Anionic dye removal from aqueous solutions using modified. Experimental results indicated that acbpv adsorbent exhibited highselectivity adsorption and efficiency for anionic dyes. Removal of a cationic dye from wastewater by adsorption onto. Adsorption of anionic dyes from aqueous solutions by calcined and uncalcined mgal layered double hydroxide 780 ye removal %0 0 x 100 2 where, q t is adsorption capacity in mgg, c o and c t are initial and final dye concentrations mgl after treatment for. In this study, we have synthesized pani with two dopants, namely, ptoluenesulfonic acid ptsa and camphorsulfonic acid csa, and used these to adsorb various dyes. Equilibrium modeling, kinetic and thermodynamic exploration. Somasundaran1 henry krumb school of mines, columbia university, nn york.
The present model study deals with the adsorption of a model anionic dye, eosin y, from wastewater using conditioned chitosan. Adsorption of cationic and anionic surfactants on natural. Adsorption of anionic and cationic dyes by activated. Adsorption of cationic and anionic dyes onto commercial.
The effect of contact time, initial dye concentration, ph and temperature were experimentally studied in batch mode to evaluate the adsorption capacity, kinetic and equilibrium. Pdf adsorption of tannery anionic dyes by modified kaolin. Adsorption of a model anionic dye, eosin y, from aqueous. The results show a tendency towards greater adsorption for anionic dyes in the ph range of 34. Coadsorption of an anionic dye in the presence of a cationic dye and a heavy metal ion by graphene oxide and photoreduced graphene oxide xiaorong zhang,ab chengbing qin, ab yani gong,ab yunrui song,ab guofeng zhang,ab ruiyun chen,ab yan gao,ab liantuan xiaoab and suotang jiaab to investigate the adsorption behavior of contaminants with di. At a ph below 2, the anions in the solution compete with the anionic dye, thereby decreasing adsorption.
Mar 18, 2020 comparing the thermodynamic parameters of adsorption of a dye from a single dye solution to binary dye solution shows higher values of. Equilibrium modeling, kinetic and thermodynamic exploration article pdf available in rsc advances 223. Adsorption of cationic and anionic surfactants on natural and synthetic carbonate materials kun ma, leyu cui, yezi dong, tianlong wang, chang da, george j. Dec 18, 2017 experimental results indicated that acbpv adsorbent exhibited highselectivity adsorption and efficiency for anionic dyes. The experimental results indicate that sorption of rr dye onto qkcf follows the langmuirmodel. Pdf adsorption of a model anionic dye, eosin y, from. Abstractin this paper, how chitosan hydrogel beads were modified by anionic surfactants sds, sdos, sdbs, aot, and dtm12 and then used for the adsorption and removal of an anionic dye congo red from aqueous solutions were described. Adsorption of anionic dye on magnesium hydroxidecoated. Selective adsorption of anionic dye from solutions by. The experimental data were analyzed by using langmuir and freundlich models of adsorption. Electrocoagulationadsorption to remove anionic and. In this regard, kenaf core fiber kcf was chemically modified by the quaternized agent 3chloro2hydroxypropyltrimethylammonium chloride to increase surface area and change the surface properties in order to improve the. Adsorption of anionicnonionic and cationicnonionic. Kinetic and equilibrium modeling of anionic dye adsorption on polyaniline emeraldine salt.
Hydrotalcitelike anionic clays have attracted considerable attention in last few decades for their capacity to remove wide range of pollutants from aqueous systems. Adsorption isotherms, kinetics and mechanism for the. Pdf effective removal of anionic textile dyes using. Adsorption of anionic dye using cationic surfactantmodified. V ariation of dye concentration with time during the adsorption of ar18, by28 and bv3 dyes onto kaolin. Adsorption can also remove soluble and insoluble organic. Characterization of the modified adsorbent was studied by bet, ftir, xrd and sem. In the present study, graphene oxide go was used for the adsorption of anionic azodyes such as acid orange 8 ao8 and direct red 23 dr23 from aqueous solutions. Adsorption of cationic and anionic dyes onto commercial kaolin 209 0 0 5 10 15 20 25 10 20 time min dye concentration, c t mgdm 3 30 40 figure 3. Adsorption of anionic dye from aqueous solution using cslf was studied in a batch system.
Adsorption properties of layered anionic claycomposites for the removal of anionic dyes from water were studied. The dye adsorption capacities of the composites were higher than the pristine clay. The kinetics of adsorption of dyes onto jsac was carried out by withdrawing and analyzing the samples at the time interval of every 5 min for the. Both these classes of dyes are toxic and cause severe problems to aquatic environment.
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